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Spectroelectrochemical investigation of nuclease active Pt(II) complexes containing pyrrole oxime

BROWSE_DETAIL_TITLE_ALTERNATE: Spectroelectrochemical investigation of nuclease active Pt(II) complexes containing pyrrole oxime

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BROWSE_DETAIL_TYPE: Article

BROWSE_DETAIL_PUBLISH_STATE: Published

BROWSE_DETAIL_FORMAT: No File

BROWSE_DETAIL_LANG: English

BROWSE_DETAIL_REFEREED: YES

BROWSE_DETAIL_ISIWOS: YES

BROWSE_DETAIL_CREATORS: Özalp Yaman, Şeniz (Author), Altunöz Erdoğan, Deniz (Author), KAYI, Hakan (Author),

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BROWSE_DETAIL_DOI: 10.1016/j.electacta.2015.01.148

BROWSE_DETAIL_URL: http://www.sciencedirect.com/science/article/pii/S0013468615001942

BROWSE_DETAIL_SOURCE: http://www.sciencedirect.com/science/article/pii/S0013468615001942


BROWSE_DETAIL_PUBLISHER: Electrochimica Acta BROWSE_DETAIL_PUBLICATION_NAME: Spectroelectrochemical Investigation of Nuclease Active Pt(II) Complexes Containing Pyrrole Oxime BROWSE_DETAIL_PUBLICATION_LOCATION: Electrochimica Acta BROWSE_DETAIL_PUBLICATION_DATE: 10-03-2015 BROWSE_DETAIL_PUBLICATION_VOLUME: 158 BROWSE_DETAIL_PUBLICATION_PAGE: 333-341


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BROWSE_DETAIL_TAB_ABSTRACT

In this paper, the electrochemical oxidation of three Pt(II) complexes containing pyrrole oxime (HL) having a general formula of [Pt(NH3)Cl(L)] (1), [Pt(L)2] (2), and K[PtCl2(L)] (3) has been investigated by in-situspectroelectrochemistry in dimethylformamide (DMF). An irreversible metal-based oxidation process occurs during the anodic scan for each of the three complexes. The electronic absorption spectral changes indicate that all the three complexes generate similar Pt(IV) compounds and free ligand. Our experimental data is supported by quantum chemistry calculations utilizing density functional theory. In addition, the frontier orbital energy distributions indicate that electron densities are localized on mainly platinum atom.


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